Formation and ligand-based reductive chemistry of bridged bis-alkylidene scandium(iii) complexes† †Electronic supplementary information (ESI) available. CCDC 1555495, 1504242, 1519012 and 1539530. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc02018j Click here for additional data file. Click here for additional data file.

Dual stimuli-induced formation of a μ-hydroxido bridged [Zn9L5(μ-OH)6]12+ half-pipe† †Electronic supplementary information (ESI) available. CCDC 1410155–1410158. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03926f Click here for additional data file. Click here for additional data file.

Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes† †Electronic supplementary information (ESI) available. CCDC 1418631–1418633. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03654b Click here for additional data file. Click here for additional data file.

A new approach to the asymmetric Mannich reaction catalyzed by chiral N,N′-dioxide–metal complexes† †Electronic supplementary information (ESI) available. CCDC 1448521 and 1480808.For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03902b Click here for additional data file. Click here for additional data file.

Highly near-IR emissive ytterbium(iii) complexes with unprecedented quantum yields† †Electronic supplementary information (ESI) available. CCDC 1501198–1501200. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05021b Click here for additional data file. Click here for additional data file.

N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P–P bond and its subsequent reactivity† †Electronic supplementary information (ESI) available: All experimental data for this manuscript including analytical and computational data. CCDC 1480947–1480953. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02343f Click here for additional data file. Click here for additional data file.

Supporting Information N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P–P bond and its subsequent reactivity. Jordan B. Waters, Thomas A. Everitt, William K. Myers and Jose M. Goicoechea* Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford, OX1 3TA, U.K. E-mail: [email protected]...